Catalytic Routes for the Conversion of Biomass Derivatives to Hydrocarbons and/or Platform Chemicals [electronic resource]

• Ngôn ngữ: eng
• Ký hiệu phân loại: 662.9 Nonfuel carbons
• Thông tin xuất bản: Los Alamos, N.M. : Oak Ridge, Tenn. : Los Alamos National Laboratory ; Distributed by the Office of Scientific and Technical Information, U.S. Dept. of Energy, 2015
• Mô tả vật lý: Size: 20 p. : , digital, PDF file.
• Bộ sưu tập: Metadata
• ID: 264745
• Chủ đề: 1. Biomass fuels(09); 2. Organic chemistry

Tóm tắt

Unprotected carbohydrates were reacted in amine-catalyzed cascade reactions with various methyl ketones to give a direct access to C-glycosides by an operationally simple protocol. As the reaction mechanism,an aldol condensation followed by an intramolecular conjugate addition is assumed.