Functionalised N-heterocyclic carbene complexes

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Tác giả: Olaf Kühl

Ngôn ngữ: eng

ISBN-10: 0470712155

ISBN-13: 978-0470712153

Ký hiệu phân loại: 547.2 Organic chemical reactions formerly 547.139

Thông tin xuất bản: Chichester, U.K. : Wiley, 2010.

Mô tả vật lý: ix, 353 pages : , illustrations ; , 26 cm.

Bộ sưu tập: Khoa học ứng dụng

ID: 277023

"N-heterocyclic carbenes (NHCs) have found increasing use as reagents for a range of organic transformations and in asymmetric organocatalysis. The performance of these molecules can be improved and tuned by functionalisation. Functionalised carbenes can anchor free carbenes to the metal site, introduce hemilability, provide a means to immobilise transition metal carbene catalysts, introduce chirality, provide a chelate ligand or bridge two metal centres. NHC can be attached to carbohydrates and campher, derived from amino acids and purines, they can be used as organocatalysts mimicking vitamin B1 or as weak "solvent" donors in lanthanide chemistry." "Functionalised N-Heterocyclic Carbene Complexes describes major trends in functionalised NHC ligands, aiming to assist readers in their attempts to develop and apply their own functionalised carbenes. After an introduction to the chemistry and behaviour of NHC, the book gives a detailed description of functionalised carbenes and their complexes according to a range of functional groups, each with a discussion of the synthetic route, structure, stability and performance." "Functionalised N-Heterocyclic Carbene Complexes is an essential guide to fine-tuning this important class of compounds for practitioners, researchers and advanced students working in synthetic organometallic and organic chemistry and catalysis." --Book Jacket.
Includes bibliographical references and index.
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